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LS-PTCR Bis(triphenylsilyl)chromate
CAS NO.: 1624-02-8

Silfluo LS-PTCR is Bis(triphenylsilyl)chromate, an organochromium(VI) coordination complex.

The molecule contains a hexavalent chromium center covalently bonded to two triphenylsilyloxy groups via Cr–O–Si linkages.

The triphenylsilyl ligands provide steric bulk and thermal stability; the Cr(VI) center is the catalytically and chemically active site.

Used as catalyst precursor in supported chromium catalyst systems for ethylene polymerization (Phillips / Union Carbide type), and as selective oxidizing reagent in pharmaceutical and fine chemical synthesis.


Typical Physical Properties of LS-PTCR Bis(triphenylsilyl)chromate


Silfluo Code:

LS-PTCR

Chemical Name:

Synonyms

Bis(triphenylsilyl)chromate

Chromic acid, bis(triphenylsilyl) ester/

Bis(triphenylsiloxy)chromium(VI) oxide

CAS No.:

EINECS No.:

1624-02-8

216-612-8

Molecular Formula:

C36H30CrO4Si2

Molecular Weight:

634.79

Appearance:

Orange to red crystalline solid(powder)

Melting Point:

156-160°C

Solubility: Soluble in chlorinated solvents and aromatics; insoluble in water.


Applications of LS-PTCR Bis(triphenylsilyl)chromate


1. HDPE and LLDPE polymerization catalyst precursor

Used as precursor in supported chromium catalyst formulation for industrial ethylene polymerization (Phillips . Union Carbide type systems).

2. Selective oxidizing reagent

Used as Cr(VI) oxidizing agent in multi-step pharmaceutical and fine chemical synthesis requiring selective functional group oxidation.

3. Organosilicon and coordination chemistry research

Used as building block in heterometallic siloxane framework and coordination polymer research.


Packing of LS-PTCR Bis(triphenylsilyl)chromate


In 20kg or 25kg specialized sealed drum.


Safety and Storage of LS-PTCR Bis(triphenylsilyl)chromate


Store at or below 25°C in a cool, dry, well-ventilated place. Keep containers tightly sealed away from moisture, heat, and incompatible reducing agents.

Shipped as hazardous substance; refer to SDS before handling, storage, transport, and use.

Shelf life: 12 months minimum from manufacture date in original unopened containers stored at or below 25°C.

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