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LS-611/HMDS Hexamethyldisilazane (HMDS)
CAS NO. 999-97-3

Silfluo LS-611 is Hexamethyldisilazane (HMDS), a trimethylsilylating agent and surface modifier.

The molecule contains two trimethylsilyl groups connected by an SiNSi linkage with an NH bond.

The SiNH reacts with active hydrogen-bearing species including silanols, hydroxyls, amines, and carboxyls, introducing trimethylsilyl groups and releasing ammonia as the sole byproduct.

Used as silylating agent in pharmaceutical and organic synthesis, adhesion promoter in semiconductor photolithography, anti-structuring process aid in HCR and LSR compounding, and surface hydrophobization agent for fumed silica and mineral fillers.

Performance equivalent to Momentive A-166, Dow Z-6079, Evonik HMDS, and Shin-Etsu HMDS3.


Typical Physical Properties of LS-611/HMDS Hexamethyldisilazane (HMDS)


Silfluo Code:

LS-611

Chemical Name:

Synonyms

Hexamethyldisilazane(HMDS)

1,1,1,3,3,3-Hexamethyldisilazane; 1,1,1-Trimethyl-N-(trimethylsilyl)silanamine;

CAS No. :

EINECS No. :

999-97-3

213-668-5

Molecular Weight:

161.39

Appearance:

Clear liquid with ammonia odor

Purity (by GC, %)

99.0 min

Density (ρ20°C, g/cm³)

0.771 ~ 0.777

Refractive Index (n25/D)

1.406~1.410

Boiling Point:

125°C(760mmHg)

Flash Point:

20 °C closed cup


Applications of LS-611/HMDS Hexamethyldisilazane (HMDS)


1. Semiconductor photolithography and CVD

Used as adhesion promoter for photoresist on silicon wafer substrates and as precursor for silicon nitride film deposition.

2. HCR and LSR silicone rubber compounding

Used as in-situ fumed silica surface treatment agent to prevent crepe hardening and improve compound processability.

3. Pharmaceutical and organic synthesis

Used as protecting group reagent for hydroxyl, amine, and carboxyl groups in API synthesis.

4. Lithium-ion battery electrolyte additive

Used as moisture and HF scavenger in Li-ion cell electrolyte systems to improve SEI layer stability and cycle life.

5. Inorganic filler and aerogel hydrophobization

Used for surface hydrophobization of fumed silica, aerogels, and mineral fillers.


Packaging of LS-611/HMDS Hexamethyldisilazane (HMDS)


In 150kg drum and 750kg IBC


Safety and Storage of LS-611/HMDS Hexamethyldisilazane (HMDS)


Keep in a cool and dry place and avoid storage in direct sunlight. Storage temperature: -50°C~45°C. Shelf life is min. 12 months. It is shipped as hazardous substance.


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