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lihmds 4039 32 1 lithium bistrimethylsilylamide lihmds
lihmds 4039 32 1 lithium bistrimethylsilylamide lihmds

LIHMDS Lithium Bistrimethylsilylamide(LiHMDS)
CAS NO. 4039-32-1

Non-nucleophilic strong bronsted base, which is generally soluble in most of the nonpolar organic solvents. Dimer in the gas phase. A mixture of monomers and dimers in tetrahydrofuran. In the absence of solvent, this compound is a dimer in solution and a trimer in solid.

Description of LIHMDS Lithium Bistrimethylsilylamide 4039-32-1


Chemical Name

Lithium bis(trimethylsilyl)amide

Synonyms

1,1,1,3,3,3-Hexamethyldisilazane lithium salt; Lithium hexamethyldisilazide

Equivalents


Molecular Formula

C6H18LiNSi2

Molecular Weight

167.32

CAS NO.

4039-32-1

EINECS NO.

223-725-6


Typical Technical Properties of LIHMDS Lithium Bistrimethylsilylamide 4039-32-1


Appearance

White powder

Melting Point

71~72°C

Flash Point

114~116°C


Applications of LIHMDS Lithium Bistrimethylsilylamide 4039-32-1


  • Used in organic reactions like generating enolates for the preparation of lactone precursors, pyranones, and cyclohexanes;

  • Used to catalyze the addition of phosphine P-H bonds to carbodiimides leading to phosphaguanidines. Also used in a novel three-step synthesis of disubstituted 1,2,5-thiadiazoles.


Package & Storage of LIHMDS Lithium Bistrimethylsilylamide 4039-32-1


  • In 50L or up to clients request.

  • Keep in cool, dry and ventilated place. Keep away from sunlight and fire sources.

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